Mechanisms of C-H bond activation: rich synergy between computation and experiment.
نویسندگان
چکیده
Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activation' (AMLA) is introduced to describe such reactions.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 30 شماره
صفحات -
تاریخ انتشار 2009